LAboratoire de Spectrochimie Infrarouge et Raman – UMR 8516
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Seminar Dr. Stefano Protti

University of Pavia, Groupe de Photochimie Organique , Italy
Phenyl cations: long live the short lived intermediates!

An appealing alternative for the generation under mild conditions of chemical intermediates is represented by the photochemical approach. This is the case of aryl cations, short-lived electrophiles (t < 100 ns) thermally accessible only under harsh conditions, but that can be smoothly generated photochemically, by irradiation of aromatic halides (chlorides, fluorides) and esters (sulfonates and phosphates) in protic solvents.

The seminar will be held on 2015.01.20 at 14:00
LASIR meeting room, basement building C5